手性硫化物於催化性氮丙啶化反應之應用
| dc.contributor | 陳榮傑 | zh_TW |
| dc.contributor | Chein, Rong-Jie | en_US |
| dc.contributor.author | 黃孟婷 | zh_TW |
| dc.contributor.author | Huang, Meng-Ting | en_US |
| dc.date.accessioned | 2019-09-04T09:21:46Z | |
| dc.date.available | 不公開 | |
| dc.date.available | 2019-09-04T09:21:46Z | |
| dc.date.issued | 2013 | |
| dc.description.abstract | 以市售的5-溴基戊酸乙脂作為起始物，經由四步驟合成而得硫化物1b-1d，接著再一步驟得到硫化物衍生物2b-2d。接著，以硫化物2b-2d作為催化劑進行不對稱氮丙啶反應之應用。 | zh_TW |
| dc.description.abstract | A novel chiral tetrahydrothiophene derivative 2b-2d was obtained from commercially available 5-Bromovalerate through a 5-steps synthetic route. We demonstrated the application of catalytic and asymmetric process for aziridination mediated by sulfur ylides. | en_US |
| dc.description.sponsorship | 化學系 | zh_TW |
| dc.identifier | GN060042066S | |
| dc.identifier.uri | http://etds.lib.ntnu.edu.tw/cgi-bin/gs32/gsweb.cgi?o=dstdcdr&s=id=%22GN060042066S%22.&%22.id.& | |
| dc.identifier.uri | http://rportal.lib.ntnu.edu.tw:80/handle/20.500.12235/100376 | |
| dc.language | 中文 | |
| dc.subject | 鋶偶極體 | zh_TW |
| dc.subject | 亞胺 | zh_TW |
| dc.subject | 氮丙啶 | zh_TW |
| dc.subject | 立體選擇性反應 | zh_TW |
| dc.subject | 有機催化劑 | zh_TW |
| dc.subject | sulfur-ylide | en_US |
| dc.subject | N-diphenylphosphinic imine | en_US |
| dc.subject | diaryl aziridine | en_US |
| dc.subject | enantioselective reaction | en_US |
| dc.subject | organocatalyst | en_US |
| dc.title | 手性硫化物於催化性氮丙啶化反應之應用 | zh_TW |
| dc.title | (Thiolan-2-yl)diphenylmethanol-catalyzed asymmetric aziridination | en_US |