三氯化金輔佐C-2炔醯胺呋喃化合物的分子內環化反應：吡咯衍生物的合成

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dc.contributor葉名倉zh_TW
dc.contributorYeh, Ming-Changen_US
dc.contributor.author林怡伶zh_TW
dc.contributor.authorLin, Yi-lingen_US
dc.date.accessioned2020-12-14T08:58:38Z
dc.date.available2020-01-01
dc.date.available2020-12-14T08:58:38Z
dc.date.issued2020
dc.description.abstract本篇論文將探討有效率合成3,4ｰ二取代吡咯的方法。在氮氣下，以甲苯為溶劑，使用C-2帶有炔醯胺側鏈的呋喃化合物，加入催化量的三氯化金進行反應，可快速得到吡咯衍生物，此吡咯衍生物帶有順式共軛烯酮的取代基，具有進行衍生反應的潛在能力。本反應的優點為溫和的反應條件、時間短及良好的產率。zh_TW
dc.description.abstractAn efficient synthesis of 3,4ｰdisubstituted pyrroles is developed. Treatment of a catalytic amount of gold(III) chloride with furans tethering a ynamide at the C-2 position in toluene under nitrogen proceeds rapidly to afford pyrrole derivatives in good yields. The product possesses a (Z)-butenonyl side chain. The functionality may lead to further transformation. The advantages of this reaction are mild reaction conditions, short reaction times, and good yields.en_US
dc.description.sponsorship化學系zh_TW
dc.identifierG060742067S
dc.identifier.urihttp://etds.lib.ntnu.edu.tw/cgi-bin/gs32/gsweb.cgi?o=dstdcdr&s=id=%22G060742067S%22.&
dc.identifier.urihttp://rportal.lib.ntnu.edu.tw:80/handle/20.500.12235/111163
dc.language中文
dc.subject路易斯酸zh_TW
dc.subject三氯化金zh_TW
dc.subject吡咯zh_TW
dc.subject炔醯胺zh_TW
dc.subject金催化zh_TW
dc.subjectLewis aciden_US
dc.subjectgold(III) chlorideen_US
dc.subjectpyrroleen_US
dc.subjectynamideen_US
dc.subjectgold-catalyzeden_US
dc.title三氯化金輔佐C-2炔醯胺呋喃化合物的分子內環化反應：吡咯衍生物的合成zh_TW
dc.titleGold(III) Chloride-Promoted Intramolecular Cyclization Reactions of C-2 Ynamide-Tethered Furans: Synthesis of Pyrrole Derivativesen_US

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