寬能隙含氮喹啉金屬螯合物之合成與鑑定及其在藍色螢光有機發光二極體之應用

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dc.contributor陳錦地zh_TW
dc.contributorChin-Ti Chenen_US
dc.contributor.author廖思虹zh_TW
dc.contributor.authorSzu-Hung Liaoen_US
dc.date.accessioned2019-09-04T09:43:38Z
dc.date.available不公開
dc.date.available2019-09-04T09:43:38Z
dc.date.issued2008
dc.description.abstract三（八羥基喹啉鋁）在有機發光二極體中是最常被使用的金屬螯合物之ㄧ。藉由將五號位置上的碳氫置換為氮，並且在四號及六號碳之位置加入甲基或是苯環取代，我們合成出三種配位基：mND、mmND以及mpND，並且與金屬鋁、鎵、銦、鎂、鋅、或鉿螯合，發展出一系列由藍色至深藍色之發光材料，並完成詳細性質之鑑定。我們將這一系列化合物作為發光層製作成元件，可得到良好的電激發光效率，並且可成功地用在主、客體發光系統中作為主體材料，製作出高效率的藍光（摻入物）元件與白光元件。zh_TW
dc.description.abstractGreen tris-(8-hydroxyquinoline)aluminum is one of the most useful metal chelates for organic light emitting diodes (OLEDs). By changing 5-position CH to N and adding methyl or phenyl substituent on 4- and 6- position of 8-hydroxylquinoline, a series of blue light-emitting metal (Al3+, Ga3+, In3+, Mg2+, Zn2+, or Hf4+) chelates 4-methyl-[1.5]-naph- thyridin-8-ol (mND), 4,6-methyl-[1,5]-naphthyridin-8-ol (mmND), and 8-methyl-2-phenyl-[1,5]naphthyridin-4-ol (mpND) were successfully synthesized and characterized. These new metal chelates are all blue to deep blue fluorescent and are suitable for wide band-gap host material for efficient dopant-based blue OLEDs and white OLEDs.en_US
dc.description.sponsorship化學系zh_TW
dc.identifierGN0695420196
dc.identifier.urihttp://etds.lib.ntnu.edu.tw/cgi-bin/gs32/gsweb.cgi?o=dstdcdr&s=id=%22GN0695420196%22.&%22.id.&
dc.identifier.urihttp://rportal.lib.ntnu.edu.tw:80/handle/20.500.12235/100626
dc.language中文
dc.subject八羥基喹啉鋁zh_TW
dc.subject金屬螯合物zh_TW
dc.subject有機發光二極體zh_TW
dc.subjectAlq3en_US
dc.subjectMetal chelateen_US
dc.subjectOLEDen_US
dc.title寬能隙含氮喹啉金屬螯合物之合成與鑑定及其在藍色螢光有機發光二極體之應用zh_TW
dc.titleSynthesis and Characterization of Wide Band-Gap Naphthyridinol Metal Chelates and their Applications to Blue Fluorescence OLEDsen_US

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