Platinum-Decorated Ruthenium Nanoparticles for Enhanced Methanol Electrooxidation
| dc.contributor | 國立臺灣師範大學化學系 | zh_tw |
| dc.contributor.author | C.-H. Chen | en_US |
| dc.contributor.author | L. S. Sarma | en_US |
| dc.contributor.author | D. -Y. Wang | en_US |
| dc.contributor.author | F.-J. Lai | en_US |
| dc.contributor.author | C.-C. AI Andra | en_US |
| dc.contributor.author | S.-H. Chang | en_US |
| dc.contributor.author | D.-G. Liu | en_US |
| dc.contributor.author | Chia-Chun Chen | en_US |
| dc.contributor.author | J.-F. Lee | en_US |
| dc.contributor.author | B.-J. Hwang | en_US |
| dc.date.accessioned | 2014-12-02T06:41:35Z | |
| dc.date.available | 2014-12-02T06:41:35Z | |
| dc.date.issued | 2010-02-08 | zh_TW |
| dc.description.abstract | A promising electrocatalyst based on the reduction of Pt2+ ions on the surface of hexagonally close-packed (hcp) Ru core nanoparticles has been prepared by a redox–transmetalation process. This simple synthetic process generates a Pt-on-Ru catalyst with a lower Pt content than commercially available Pt[BOND]Ru electrocatalysts and with a long-range ordered hcp structure, which can significantly reduce the Pt loading. X-Ray absorption spectroscopy of the Pt-on-Ru catalyst reveals pronounced electronic modifications when compared to the commercial Pt[BOND]Ru black catalyst. The Pt-on-Ru catalyst exhibits a higher mass-specific current than the Pt[BOND]Ru black catalyst in solution in 0.5 m H2SO4 with 10 vol. % CH3OH under the conditions of rotating disk experiments. Further optimization of this synthetic procedure may yield even more active electrocatalysts with a significant reduction in noble metal loadings. | en_US |
| dc.description.uri | http://onlinelibrary.wiley.com/doi/10.1002/cctc.200900051/pdf | zh_TW |
| dc.identifier | ntnulib_tp_C0301_01_062 | zh_TW |
| dc.identifier.issn | 1867-3880 | zh_TW |
| dc.identifier.uri | http://rportal.lib.ntnu.edu.tw/handle/20.500.12235/42346 | |
| dc.language | en_US | zh_TW |
| dc.publisher | Wiley-VCH Verlag | en_US |
| dc.relation | ChemCatChem, 2(2), 159-166. | en_US |
| dc.relation.uri | http://dx.doi.org/10.1002/cctc.200900051 | zh_TW |
| dc.subject.other | electrocatalysis | en_US |
| dc.subject.other | electrochemistry | en_US |
| dc.subject.other | fuel cells | en_US |
| dc.subject.other | nanoparticles | en_US |
| dc.subject.other | X-ray absorption spectroscopy | en_US |
| dc.title | Platinum-Decorated Ruthenium Nanoparticles for Enhanced Methanol Electrooxidation | en_US |