蒽醌類化合物之合成

dc.contributor.author劉英玫zh_tw
dc.contributor.author許順吉zh_tw
dc.date.accessioned2014-10-27T15:22:59Z
dc.date.available2014-10-27T15:22:59Z
dc.date.issued1988-06-??zh_TW
dc.description.abstract本文由對氯苯酚和鄰苯二甲酸酐的縮合反應和取代反應合成化合物1~4,由鄰苯二酚合鄰苯二甲酸酐的縮合反應和取代反應合成化合物5和6,由鄰甲苯酚和鄰苯二甲酸酐的縮合反應合成化合物7,由苯酚和鄰苯二甲酸酐的縮合反應和取代反應合成化合物8~10,由沒食子酸和苯甲酸的縮合反應和取代反應合成化合物11 和12,由沒食子酸的自身縮合反應和取代反應合成化合物12和14,等共計十四種??類衍生物,其中化合物10,12,和14可能為新化合物。這類化合物在3500cm-1~3200 cm-1間之O-H伸縮震動吸收頻率明顯地受分子內氫鍵的影響,有分子內氫鍵者吸收頻率較大;在1780cm-1~1640 cm-1間的C=O伸縮震動吸收頻率明顯地受分子內氫鍵支配,有分子內氫鍵者吸收頻率降低,其他的取代基對C=O的吸收頻率影響較小。zh_tw
dc.description.abstractFourteen anthraquinone derivatives had been synthesized via six major routes: p-chlorophenol and phthalic anhydride via the condenstion and substitution reactions led compound 1~4 ; pyrocatechol and phthalic anhydride via the condensation and substitution reactions led compound 5~6; o-cresol and phthalic anhydride via the condensation reaction led compound 7; phenol and phthalic anhydride via the condensation and substitution reactions led compound .8~10; gallic acid and benzole acid via the condensation and substitution reactions led compound 11~12; gallic acid via the self-condensation and substitution reactions led compound 13~14. The c=o and O-H stretching vibration of these compounds were found in the regions of 1780-1640 cm-1 and 3500-3200cm-1, and the detailed differences were discussed.en_US
dc.identifier13441DEE-CE9C-160B-3DF0-2D22B929B5EDzh_TW
dc.identifier.urihttp://rportal.lib.ntnu.edu.tw/handle/20.500.12235/16903
dc.language中文zh_TW
dc.publisher國立臺灣師範大學研究發展處zh_tw
dc.publisherOffice of Research and Developmenten_US
dc.relation(33),473-483zh_TW
dc.relation.ispartof師大學報zh_tw
dc.subject.other蒽醌類化合物zh_tw
dc.title蒽醌類化合物之合成zh-tw
dc.title.alternativeSynthesis of Anthraquinone Derivativeszh_tw

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