陳榮傑Chein, Rong-Jie黃孟婷Huang, Meng-Ting2019-09-04不公開2019-09-042013http://etds.lib.ntnu.edu.tw/cgi-bin/gs32/gsweb.cgi?o=dstdcdr&s=id=%22GN060042066S%22.&%22.id.&http://rportal.lib.ntnu.edu.tw:80/handle/20.500.12235/100376以市售的5-溴基戊酸乙脂作為起始物，經由四步驟合成而得硫化物1b-1d，接著再一步驟得到硫化物衍生物2b-2d。接著，以硫化物2b-2d作為催化劑進行不對稱氮丙啶反應之應用。A novel chiral tetrahydrothiophene derivative 2b-2d was obtained from commercially available 5-Bromovalerate through a 5-steps synthetic route. We demonstrated the application of catalytic and asymmetric process for aziridination mediated by sulfur ylides.鋶偶極體亞胺氮丙啶立體選擇性反應有機催化劑sulfur-ylideN-diphenylphosphinic iminediaryl aziridineenantioselective reactionorganocatalyst