Please use this identifier to cite or link to this item: http://rportal.lib.ntnu.edu.tw:80/handle/77345300/42317
Title: Crystallization, Melting and Morphology of PEO in PEO/MWNT-g-PMMA Blends
Authors: 國立臺灣師範大學化學系
Y.-T. Shieh
G.-L. Liu
K.-C. Huang
Chia-Chun Chen
Issue Date: 21-Nov-2005
Publisher: ELSEVIER
Abstract: The dispersion of multi-walled carbon nanotubes (MWNTs) in crystalline poly(ethylene oxide) (PEO) is significantly improved by grafting with poly(methyl methacrylate) (PMMA) on surface of MWNTs via emulsion reactions. The synthesized MWNTs-g-PMMA is soluble in solvents that can dissolve PMMA and is well dispersed in PEO. The effects of the MWNTs-g-PMMA on PEO crystallization and its use as a reinforcement for PEO are investigated using DMA, DSC, POM, and SAXS. DMA data show that the PEO/MWNTs-g-PMMA blends containing up to 30 wt% MWNTs-g-PMMA are compatible. DSC data show the crystallization of PEO is enhanced by the MWNTs-g-PMMA, accompanying with a decreased thickness of crystal layers and an increased thickness of amorphous layers of the PEO lamellar stacks, in combination with SAXS data.
URI: http://rportal.lib.ntnu.edu.tw/handle/77345300/42317
ISSN: 0032-3861
Other Identifiers: ntnulib_tp_C0301_01_033
Appears in Collections:教師著作

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